(1alpha,2alpha,5alpha)-6,6-dimethylbicyclo[3.1.1]heptane-2-methanol
- CAS: 15358-91-5
- Purity: 99%
- Buy Quality (1alpha,2alpha,5alpha)-6,6-dimethylbicyclo[3.1.1]heptane-2-methanol 15358-91-5 In Stock with Immediately Delivery
Buy Quality (1alpha,2alpha,5alpha)-6,6-dimethylbicyclo[3.1.1]heptane-2-methanol 15358-91-5 In Stock with Immediately Delivery
- Molecular Formula: C10H18O
- Molecular Weight: 154.252
- Boiling Point: 219.5°Cat760mmHg
- PKA: 14.99±0.10(Predicted)
- Flash Point: 96°C
- PSA： 20.23000
- Density: 0.95g/cm3
- LogP: 2.05100
15358-91-5 Relevant articles
Visible-Light-Mediated Aerobic Oxidation of Organoboron Compounds Using in Situ Generated Hydrogen Peroxide
Weng, Wei-Zhi,Liang, Hao,Zhang, Bo
, p. 4979 - 4983 (2018/08/24)
A simple and general visible-light-media...
Development of a flow method for the hydroboration/oxidation of olefins
Souto, José A.,Stockman, Robert A.,Ley, Steven V.
, p. 3871 - 3877 (2015/03/30)
A method for the continuous preparation ...
HYDRONOPOL DERIVATIVES AS AGONISTS ON HUMAN ORL1 RECEPTORS
-
Page/Page column 6, (2010/02/13)
The invention relates to a group of hydr...
PS-COD and PS-9-BBN: Polymer-supported reagents for solution-phase parallel synthesis
Revell, Jefferson D.,Doerner, Barbara,White, Peter D.,Ganesan
, p. 831 - 833 (2007/10/03)
(Chemical Equation Presented) 1,5-Cycloo...
15358-91-5 Process route
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-
127-91-3,25719-60-2
(1R,5R)-(+)-β-pinene
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-
473-01-8,514-99-8,15358-91-5,15358-92-6,51152-12-6,53369-17-8,73136-30-8,132203-71-5
cis-myrtanol
| Conditions | Yield |
|---|---|
|
With
C11H7F17S(1+)B(1-)H3; 3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl methyl sulfide;
In
FC-72; dichloromethane;
|
93%
|
|
(1R,5R)-(+)-β-pinene;
With
dimethyl sulfide borane;
In
tetrahydrofuran;
at 0 ℃;
for 0.5h;
With
sodium hydroxide; dihydrogen peroxide;
In
tetrahydrofuran; ethanol; water;
at 0 - 35 ℃;
for 1h;
Heating / reflux;
|
93%
|
|
(1R,5R)-(+)-β-pinene;
With
borane-THF;
In
tetrahydrofuran;
at 25 ℃;
for 0.0138889h;
Flow reactor;
With
dihydrogen peroxide; sodium hydroxide;
In
tetrahydrofuran; ethanol; water;
at 20 ℃;
for 0.00555556h;
Reagent/catalyst;
Temperature;
Solvent;
Flow reactor;
|
92%
|
|
(1R,5R)-(+)-β-pinene;
With
C13H31BS;
In
tetrahydrofuran;
at 20 ℃;
for 2h;
With
sodium hydroxide; dihydrogen peroxide;
at 20 ℃;
for 8h;
|
78%
|
|
With
sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; sodium iodide;
Yield given. Multistep reaction;
1.) diglyme, 25 deg C, electrolysis, 2.) 25 deg C, 2 h;
|
|
|
With
sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; sodium iodide;
multistep reaction, effect of supporting electrolyte on electrochemical hydroboration;
|
|
|
(1R,5R)-(+)-β-pinene;
With
sodium hydroxide; lithium borohydride; sulfuric acid;
In
tetrahydrofuran; water;
With
chlorine dioxide;
In
water;
|
|
|
With
sodium hydroxide; sodium tetrahydroborate; dihydrogen peroxide; sodium iodide;
Yield given. Multistep reaction;
1) diglyme, r.t., electrolysis, Pt foil anode, stainless plate cathode;
|
|
|
(1R,5R)-(+)-β-pinene;
With
borane-diisoamyl sulfide;
In
tetrahydrofuran;
at 20 ℃;
for 1h;
With
sodium hydroxide; dihydrogen peroxide;
In
tetrahydrofuran;
at 20 ℃;
for 3h;
Further stages.;
|
-
-
23727-16-4
myrtenal
-
-
473-01-8,514-99-8,15358-91-5,15358-92-6,51152-12-6,53369-17-8,73136-30-8,132203-71-5
cis-myrtanol
| Conditions | Yield |
|---|---|
|
With
platinum;
Hydrogenation;
|
|
|
With
kieselguhr; cyclohexane; nickel;
at 55 ℃;
under 47808 Torr;
Hydrogenation;
|
15358-91-5 Upstream products
-
23727-16-4
myrtenal
-
6712-78-3
myrtenol
-
1118071-19-4
2-chloromethyl-6,6-dimethylbicyclo[3.1.1]heptane
-
515-00-4
(+/-)-myrtenol
15358-91-5 Downstream products
-
4764-14-1
(+/-)-Myrtanal
-
4764-14-1
(+/-)-Isomyrtanal
-
29021-36-1
(1R )-10-Acetoxy-cis -pinan
-
81510-28-3
(1R,2R,5R)-2-[2-(Diphenyl-phosphinoyl)-ethoxymethyl]-6,6-dimethyl-bicyclo[3.1.1]heptane
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